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Resolving Oxygenation Pathways in Manganese-Catalyzed C(sp(3))–H Functionalization via Radical and Cationic Intermediates

[Image: see text] The C(sp(3))–H bond oxygenation of the cyclopropane-containing mechanistic probes 6-tert-butylspiro[2.5]octane and spiro[2.5]octane with hydrogen peroxide catalyzed by manganese complexes bearing aminopyridine tetradentate ligands has been studied. Mixtures of unrearranged and rear...

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Detalles Bibliográficos
Autores principales:	Galeotti, Marco, Vicens, Laia, Salamone, Michela, Costas, Miquel, Bietti, Massimo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052745/ https://www.ncbi.nlm.nih.gov/pubmed/35417154 http://dx.doi.org/10.1021/jacs.2c01466

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