From Serendipity to Rational Design: Heteroleptic Dirhodium Amidate Complexes for Diastereodivergent Asymmetric Cyclopropanation

[Image: see text] A heteroleptic dirhodium paddlewheel complex comprising three chiral carboxylate ligands and one achiral acetamidate ligand has recently been found to be uniquely effective in catalyzing the asymmetric cyclopropanation of olefins with α-stannylated (silylated and germylated) α-diaz...

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Detalles Bibliográficos
Autores principales: Caló, Fabio Pasquale, Zimmer, Anne, Bistoni, Giovanni, Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052758/
https://www.ncbi.nlm.nih.gov/pubmed/35420801
http://dx.doi.org/10.1021/jacs.2c02258

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052758/
https://www.ncbi.nlm.nih.gov/pubmed/35420801
http://dx.doi.org/10.1021/jacs.2c02258

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