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Carbon monoxide formation from trimethylamine-boranecarboxylate: DFT studies of S(N)i and chelotropic mechanisms
Trimethylamine-boranecarboxylic acid (CH(3))(3)N-BH(2)COOH and other amine carboxyboranes have been observed to undergo slow decarbonylation in neutral aqueous solution. This reaction, when it occurs in vivo, may have a therapeutic effect by delivering low concentrations of carbon monoxide over an e...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052891/ https://www.ncbi.nlm.nih.gov/pubmed/35493645 http://dx.doi.org/10.1039/d0ra01572e |