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Carbon monoxide formation from trimethylamine-boranecarboxylate: DFT studies of S(N)i and chelotropic mechanisms

Trimethylamine-boranecarboxylic acid (CH(3))(3)N-BH(2)COOH and other amine carboxyboranes have been observed to undergo slow decarbonylation in neutral aqueous solution. This reaction, when it occurs in vivo, may have a therapeutic effect by delivering low concentrations of carbon monoxide over an e...

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Detalles Bibliográficos
Autores principales: Keller, John W., Ayudhya, Theppawut I., Dingra, Nin N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052891/
https://www.ncbi.nlm.nih.gov/pubmed/35493645
http://dx.doi.org/10.1039/d0ra01572e

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