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An indication of spin-transition accompanied by an order-disorder structural transformation in [Ni(phpyNO)(2)(NCS)(2)] (phpyNO = tert-butyl 5-phenyl-2-pyridyl nitroxide)
Reaction of nickel(ii) thiocyanate and tert-butyl 5-phenyl-2-pyridyl nitroxide (phpyNO) afforded a 2p–3d–2p heterospin triad [Ni(phpyNO)(2)(NCS)(2)]. The compound crystallizes in the orthorhombic Pbcn space group. The whole molecule is crystallographically independent. The torsion angles around Ni–O...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052934/ https://www.ncbi.nlm.nih.gov/pubmed/35493632 http://dx.doi.org/10.1039/d0ra02041a |