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Catalyzed M–C coupling reactions in the synthesis of σ-(pyridylethynyl)dicarbonylcyclopentadienyliron complexes

The reactions between terminal ethynylpyridines, (trimethylsilyl)ethynylpyridines and cyclopentadienyliron dicarbonyl iodide were studied under Pd/Cu-catalyzed conditions to develop a synthetic approach to the σ-alkynyl iron complexes Cp(CO)(2)Fe–C[triple bond, length as m-dash]C–R (R = ortho-, meta...

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Detalles Bibliográficos
Autores principales: Verpekin, Victor V., Semeikin, Oleg V., Vasiliev, Alexander D., Kondrasenko, Alexander A., Belousov, Yuri A., Ustynyuk, Nikolai A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9053414/
https://www.ncbi.nlm.nih.gov/pubmed/35521461
http://dx.doi.org/10.1039/d0ra02333g