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Extremely fast-charging lithium ion battery enabled by dual-gradient structure design

Extremely fast-charging lithium-ion batteries are highly desirable to shorten the recharging time for electric vehicles, but it is hampered by the poor rate capability of graphite anodes. Here, we present a previously unreported particle size and electrode porosity dual-gradient structure design in...

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Detalles Bibliográficos
Autores principales: Lu, Lei-Lei, Lu, Yu-Yang, Zhu, Zheng-Xin, Shao, Jia-Xin, Yao, Hong-Bin, Wang, Shaogang, Zhang, Tian-Wen, Ni, Yong, Wang, Xiu-Xia, Yu, Shu-Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054020/
https://www.ncbi.nlm.nih.gov/pubmed/35486719
http://dx.doi.org/10.1126/sciadv.abm6624
Descripción
Sumario:Extremely fast-charging lithium-ion batteries are highly desirable to shorten the recharging time for electric vehicles, but it is hampered by the poor rate capability of graphite anodes. Here, we present a previously unreported particle size and electrode porosity dual-gradient structure design in the graphite anode for achieving extremely fast-charging lithium ion battery under strict electrode conditions. We develop a polymer binder–free slurry route to construct this previously unreported type particle size-porosity dual-gradient structure in the practical graphite anode showing the extremely fast-charging capability with 60% of recharge in 10 min. On the basis of dual-gradient graphite anode, we demonstrate extremely fast-charging lithium ion battery realizing 60% recharge in 6 min and high volumetric energy density of 701 Wh liter(−1) at the high charging rate of 6 C.