Restriction of the conrotatory motion in photo-induced 6π electrocyclic reaction: formation of the excited state of the closed-ring isomer in the cyclization

The electrocyclic reaction dynamics of a photochromic dithiazolylarylene derivative, 2,3-dithiazolylbenzothiophene (DTA) was investigated by using time-resolved transient absorption and fluorescence spectroscopies. The closed-ring isomer of DTA undergoes cycloreversion through the conical intersecti...

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Detalles Bibliográficos
Autores principales: Nagasaka, Tatsuhiro, Sotome, Hikaru, Morikawa, Soichiro, Uriarte, Lucas Martinez, Sliwa, Michel, Kawai, Tsuyoshi, Miyasaka, Hiroshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054205/
https://www.ncbi.nlm.nih.gov/pubmed/35520419
http://dx.doi.org/10.1039/d0ra03523h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054205/
https://www.ncbi.nlm.nih.gov/pubmed/35520419
http://dx.doi.org/10.1039/d0ra03523h

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