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X-ray absorption spectroscopy of archetypal chromium porphyrin and corrole derivatives
A combination of Cr K-edge XAS and DFT calculations have been performed on archetypal chromium porphyrinoid complexes Cr(IV)[TMP]O (2) and Cr(V)[TPC]O (3), and the results have been compared to the reference compound Cr(III)[TPP]Cl (1), where TPP(2−), TMP(2−), and TPC(3−) are the anions of meso-tetr...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054285/ https://www.ncbi.nlm.nih.gov/pubmed/35517776 http://dx.doi.org/10.1039/d0ra02335c |