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X-ray absorption spectroscopy of archetypal chromium porphyrin and corrole derivatives

A combination of Cr K-edge XAS and DFT calculations have been performed on archetypal chromium porphyrinoid complexes Cr(IV)[TMP]O (2) and Cr(V)[TPC]O (3), and the results have been compared to the reference compound Cr(III)[TPP]Cl (1), where TPP(2−), TMP(2−), and TPC(3−) are the anions of meso-tetr...

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Detalles Bibliográficos
Autores principales: Cao, Rui, Thomas, Kolle E., Ghosh, Abhik, Sarangi, Ritimukta
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054285/
https://www.ncbi.nlm.nih.gov/pubmed/35517776
http://dx.doi.org/10.1039/d0ra02335c