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The Baeyer–Villiger rearrangement with metal triflates: new developments toward mechanism
Based on MS analysis, the mechanism of the Baeyer–Villiger oxidation of cyclic ketones with hydrogen peroxide using metal triflates (Ga(OTf)(3) and Er(OTf)(3)) as catalysts was proposed. In the case of cyclohexanone as a substrate, dimeric, trimeric and tetrameric peroxide structures were detected....
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054370/ https://www.ncbi.nlm.nih.gov/pubmed/35518740 http://dx.doi.org/10.1039/d0ra03335a |