The Baeyer–Villiger rearrangement with metal triflates: new developments toward mechanism

Based on MS analysis, the mechanism of the Baeyer–Villiger oxidation of cyclic ketones with hydrogen peroxide using metal triflates (Ga(OTf)(3) and Er(OTf)(3)) as catalysts was proposed. In the case of cyclohexanone as a substrate, dimeric, trimeric and tetrameric peroxide structures were detected....

Descripción completa

Detalles Bibliográficos
Autores principales: Latos, Piotr, Siewniak, Agnieszka, Sitko, Magdalena, Chrobok, Anna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054370/
https://www.ncbi.nlm.nih.gov/pubmed/35518740
http://dx.doi.org/10.1039/d0ra03335a
Descripción
Sumario:Based on MS analysis, the mechanism of the Baeyer–Villiger oxidation of cyclic ketones with hydrogen peroxide using metal triflates (Ga(OTf)(3) and Er(OTf)(3)) as catalysts was proposed. In the case of cyclohexanone as a substrate, dimeric, trimeric and tetrameric peroxide structures were detected.

Ejemplares similares