The Baeyer–Villiger rearrangement with metal triflates: new developments toward mechanism

Based on MS analysis, the mechanism of the Baeyer–Villiger oxidation of cyclic ketones with hydrogen peroxide using metal triflates (Ga(OTf)(3) and Er(OTf)(3)) as catalysts was proposed. In the case of cyclohexanone as a substrate, dimeric, trimeric and tetrameric peroxide structures were detected....

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Autores principales: Latos, Piotr, Siewniak, Agnieszka, Sitko, Magdalena, Chrobok, Anna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054370/
https://www.ncbi.nlm.nih.gov/pubmed/35518740
http://dx.doi.org/10.1039/d0ra03335a
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author Latos, Piotr
Siewniak, Agnieszka
Sitko, Magdalena
Chrobok, Anna
author_facet Latos, Piotr
Siewniak, Agnieszka
Sitko, Magdalena
Chrobok, Anna
author_sort Latos, Piotr
collection PubMed
description Based on MS analysis, the mechanism of the Baeyer–Villiger oxidation of cyclic ketones with hydrogen peroxide using metal triflates (Ga(OTf)(3) and Er(OTf)(3)) as catalysts was proposed. In the case of cyclohexanone as a substrate, dimeric, trimeric and tetrameric peroxide structures were detected.
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spelling pubmed-90543702022-05-04 The Baeyer–Villiger rearrangement with metal triflates: new developments toward mechanism Latos, Piotr Siewniak, Agnieszka Sitko, Magdalena Chrobok, Anna RSC Adv Chemistry Based on MS analysis, the mechanism of the Baeyer–Villiger oxidation of cyclic ketones with hydrogen peroxide using metal triflates (Ga(OTf)(3) and Er(OTf)(3)) as catalysts was proposed. In the case of cyclohexanone as a substrate, dimeric, trimeric and tetrameric peroxide structures were detected. The Royal Society of Chemistry 2020-06-04 /pmc/articles/PMC9054370/ /pubmed/35518740 http://dx.doi.org/10.1039/d0ra03335a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Latos, Piotr
Siewniak, Agnieszka
Sitko, Magdalena
Chrobok, Anna
The Baeyer–Villiger rearrangement with metal triflates: new developments toward mechanism
title The Baeyer–Villiger rearrangement with metal triflates: new developments toward mechanism
title_full The Baeyer–Villiger rearrangement with metal triflates: new developments toward mechanism
title_fullStr The Baeyer–Villiger rearrangement with metal triflates: new developments toward mechanism
title_full_unstemmed The Baeyer–Villiger rearrangement with metal triflates: new developments toward mechanism
title_short The Baeyer–Villiger rearrangement with metal triflates: new developments toward mechanism
title_sort baeyer–villiger rearrangement with metal triflates: new developments toward mechanism
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054370/
https://www.ncbi.nlm.nih.gov/pubmed/35518740
http://dx.doi.org/10.1039/d0ra03335a
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