Cargando…

The Baeyer–Villiger rearrangement with metal triflates: new developments toward mechanism

Based on MS analysis, the mechanism of the Baeyer–Villiger oxidation of cyclic ketones with hydrogen peroxide using metal triflates (Ga(OTf)(3) and Er(OTf)(3)) as catalysts was proposed. In the case of cyclohexanone as a substrate, dimeric, trimeric and tetrameric peroxide structures were detected....

Descripción completa

Detalles Bibliográficos
Autores principales:	Latos, Piotr, Siewniak, Agnieszka, Sitko, Magdalena, Chrobok, Anna
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054370/ https://www.ncbi.nlm.nih.gov/pubmed/35518740 http://dx.doi.org/10.1039/d0ra03335a

Ejemplares similares

Perdecanoic acid as a safe and stable medium-chain peracid for Baeyer–Villiger oxidation of cyclic ketones to lactones
por: Sitko, Magdalena, et al.
Publicado: (2019)

Chemo-Enzymatic Baeyer–Villiger Oxidation Facilitated with Lipases Immobilized in the Supported Ionic Liquid Phase
por: Szelwicka, Anna, et al.
Publicado: (2021)

A Carbonate-Forming Baeyer-Villiger Monooxygenase
por: Hu, Youcai, et al.
Publicado: (2014)

Aqueous microdroplets containing only ketones or aldehydes undergo Dakin and Baeyer–Villiger reactions
por: Gao, Dan, et al.
Publicado: (2019)

A tellura-Baeyer–Villiger oxidation: one-step transformation of tellurophene into chiral tellurinate lactone
por: Wang, Shitao, et al.
Publicado: (2021)

Structural and Catalytic Characterization of a Fungal Baeyer-Villiger Monooxygenase
por: Ferroni, Felix Martin, et al.
Publicado: (2016)

Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer–Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones
por: Vil', Vera A., et al.
Publicado: (2020)

Baeyer-Villiger Oxidation of Some C(19) Steroids by Penicillium lanosocoeruleum
por: Świzdor, Alina
Publicado: (2013)

A retro Baeyer–Villiger reaction: electrochemical reduction of [60]fullerene-fused lactones to [60]fullerene-fused ketones
por: Niu, Chuang, et al.
Publicado: (2019)

Asymmetric Baeyer–Villiger oxidation: classical and parallel kinetic resolution of 3-substituted cyclohexanones and desymmetrization of meso-disubstituted cycloketones
por: Wu, Wangbin, et al.
Publicado: (2019)

Exhaustive Baeyer–Villiger oxidation: a tailor-made post-polymerization modification to access challenging poly(vinyl acetate) copolymers
por: Ma, Pengfei, et al.
Publicado: (2022)

Catalyst Control over Regio- and Enantioselectivity in Baeyer–Villiger Oxidations of Functionalized Ketones
por: Romney, David K., et al.
Publicado: (2014)

The Origin and Evolution of Baeyer—Villiger Monooxygenases (BVMOs): An Ancestral Family of Flavin Monooxygenases
por: Mascotti, Maria Laura, et al.
Publicado: (2015)

Application of a thermostable Baeyer–Villiger monooxygenase for the synthesis of branched polyester precursors
por: Delgove, Marie AF, et al.
Publicado: (2018)

Keggin-Type Heteropoly Salts as Bifunctional Catalysts in Aerobic Baeyer-Villiger Oxidation
por: Pamin, Katarzyna, et al.
Publicado: (2018)

Cloning and characterization of the Type I Baeyer–Villiger monooxygenase from Leptospira biflexa
por: Ceccoli, Romina D., et al.
Publicado: (2017)

Lipase-Catalyzed Baeyer-Villiger Oxidation of Cellulose-Derived Levoglucosenone into (S)-γ-Hydroxymethyl-α,β-Butenolide: Optimization by Response Surface Methodology
por: Teixeira, Andreia R. S., et al.
Publicado: (2016)

Bioinformatic Mining and Structure-Activity Profiling of Baeyer-Villiger Monooxygenases from Mycobacterium tuberculosis
por: Tomas, Nicolas, et al.
Publicado: (2022)

Mutations Increasing Cofactor Affinity, Improve Stability and Activity of a Baeyer–Villiger Monooxygenase
por: Mansouri, Hamid R., et al.
Publicado: (2022)

Lipase-mediated Baeyer–Villiger oxidation of benzylcyclopentanones in ester solvents and deep eutectic solvents
por: Mazur, Marcelina, et al.
Publicado: (2022)

Cu(ii)/SPDO complex catalyzed asymmetric Baeyer–Villiger oxidation of 2-arylcyclobutanones and its application for the total synthesis of eupomatilones 5 and 6
por: Zhang, Chang-Sheng, et al.
Publicado: (2022)

Expanding the set of rhodococcal Baeyer–Villiger monooxygenases by high-throughput cloning, expression and substrate screening
por: Riebel, A., et al.
Publicado: (2012)

Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation
por: Ma, Xiaofeng, et al.
Publicado: (2020)

Mining the Genome of Streptomyces leeuwenhoekii: Two New Type I Baeyer–Villiger Monooxygenases From Atacama Desert
por: Gran-Scheuch, Alejandro, et al.
Publicado: (2018)

The Substrate-Bound Crystal Structure of a Baeyer–Villiger Monooxygenase Exhibits a Criegee-like Conformation
por: Yachnin, Brahm J., et al.
Publicado: (2012)

Cloning, expression and characterization of a versatile Baeyer-Villiger monooxygenase from Dietzia sp. D5
por: Bisagni, Serena, et al.
Publicado: (2014)

Microbial-Catalyzed Baeyer–Villiger Oxidation for 3,4-seco-Triterpenoids as Potential HMGB1 Inhibitors
por: Shen, Pingping, et al.
Publicado: (2022)

First chemo-enzymatic synthesis of the (R)-Taniguchi lactone and substrate profiles of CAMO and OTEMO, two new Baeyer–Villiger monooxygenases
por: Rudroff, Florian, et al.
Publicado: (2016)

Isolation and initial characterization of a novel type of Baeyer–Villiger monooxygenase activity from a marine microorganism
por: Willetts, Andrew, et al.
Publicado: (2012)

Cloning, overexpression and biocatalytic exploration of a novel Baeyer-Villiger monooxygenase from Aspergillus fumigatus Af293
por: Mascotti, Maria Laura, et al.
Publicado: (2013)

In vitro characterization of an enzymatic redox cascade composed of an alcohol dehydrogenase, an enoate reductases and a Baeyer–Villiger monooxygenase
por: Oberleitner, Nikolin, et al.
Publicado: (2014)

Alternative Splicing of the Aflatoxin-Associated Baeyer–Villiger Monooxygenase from Aspergillus flavus: Characterisation of MoxY Isoforms
por: Tolmie, Carmien, et al.
Publicado: (2018)

Exploring the Temperature Effect on Enantioselectivity of a Baeyer‐Villiger Biooxidation by the 2,5‐DKCMO Module: The SLM Approach
por: Röllig, Robert, et al.
Publicado: (2022)

Investigation of a New Type I Baeyer–Villiger Monooxygenase from Amycolatopsis thermoflava Revealed High Thermodynamic but Limited Kinetic Stability
por: Mansouri, Hamid R., et al.
Publicado: (2020)

Erratum to: Cloning, overexpression and biocatalytic exploration of a novel Baeyer-Villiger monooxygenase from Aspergillus fumigatus Af293
por: Mascotti, Maria Laura, et al.
Publicado: (2014)

Cobalt-Tetraamide-Phthalocyanine Immobilized on Fe(3)O(4)/Chitosan Microspheres as an Efficient Catalyst for Baeyer–Villiger Oxidation
por: Tang, Zhilin, et al.
Publicado: (2020)

Catalytic and Stoichiometric Baeyer–Villiger Oxidation Mediated by Nonheme Peroxo-Diiron(III), Acylperoxo, and Iodosylbenzene Iron(III) Intermediates
por: Lakk-Bogáth, Dóra, et al.
Publicado: (2022)

Phosphorous-Doped Graphitic Material as a Solid Acid Catalyst for Microwave-Assisted Synthesis of β-Ketoenamines and Baeyer–Villiger Oxidation
por: Maity, Sayantan, et al.
Publicado: (2020)

Photobiocatalytic Oxyfunctionalization with High Reaction Rate using a Baeyer–Villiger Monooxygenase from Burkholderia xenovorans in Metabolically Engineered Cyanobacteria
por: Erdem, Elif, et al.
Publicado: (2021)

A Cold-Active Flavin-Dependent Monooxygenase from Janthinobacterium svalbardensis Unlocks Applications of Baeyer–Villiger Monooxygenases at Low Temperature
por: Chánique, Andrea M., et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_8d3qnig8fdjm5k6lae24kc1qvj