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Elucidating sensing mechanisms of a pyrene excimer-based calix[4]arene for ratiometric detection of Hg(ii) and Ag(i) and chemosensor behaviour as INHIBITION or IMPLICATION logic gates

This article reports the synthesis and characterisation of two lower rim calix[4]arene derivatives with thiourea as spacer and pyrene or methylene–pyrene as fluorophore. Both derivatives exhibit a fluorimetric response towards Hg(2+), Ag(+) and Cu(2+). Only methylene–pyrenyl derivative 2 allows for...

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Detalles Bibliográficos
Autores principales: Rodríguez-Lavado, Julio, Lorente, Alejandro, Flores, Erick, Ochoa, Andrés, Godoy, Fernando, Jaque, Pablo, Saitz, Claudio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054513/
https://www.ncbi.nlm.nih.gov/pubmed/35516608
http://dx.doi.org/10.1039/d0ra04092d