Ancillary ligand electro-activity effects towards phenyl acetylene homocoupling reaction by a nickel(ii) complex of a non-innocent O-amino phenol ligand: a mechanistic insight

A new Ni(ii) complex, was synthesized from the reaction of a non-innocent o-aminophenol ligand, and Ni(OAc)(2). The crystal structure of Ni(II)L(2)(NIS) (in which, IS stands for iminosemiquinone radical ligand with cyanide (shown by N in NIS) substituent on phenolate rings) exhibits the square plana...

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Detalles Bibliográficos
Autores principales: Nasibipour, Mina, Safaei, Elham, Masoumpour, Marziyeh Sadat, Wojtczak, Andrzej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055111/
https://www.ncbi.nlm.nih.gov/pubmed/35516191
http://dx.doi.org/10.1039/d0ra04362a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055111/
https://www.ncbi.nlm.nih.gov/pubmed/35516191
http://dx.doi.org/10.1039/d0ra04362a

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