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Base-iodine-promoted metal-catalyst-free reactions of [60]fullerene with β-keto esters for the selective formation of [60]fullerene derivatives
In this study, methanofullerenes and 2′,3′-dihydrofuran C(60) derivatives were selectively synthesized in high yields via the reactions of C(60) with β-keto esters under mild conditions by controlling the addition sequence and molar ratio of iodine and base. The structures of the products were deter...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055150/ https://www.ncbi.nlm.nih.gov/pubmed/35516172 http://dx.doi.org/10.1039/d0ra04996d |