Electrochemically driven, cobalt–carbon bond-mediated direct intramolecular cyclic and acyclic perfluoroalkylation of (hetero)arenes using X(CF(2))(4)X

A proof-of-concept for the one-step, synthetically challenging cyclic and acyclic perfluoroalkylation of (hetero)arenes driven by the valence change of a vitamin B(12) derivative as a cobalt catalyst in the presence of fluoroalkylating reagents (X(CF(2))(4)X) is presented. The consecutive formation...

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Detalles Bibliográficos
Autores principales: Cui, Luxia, Ono, Toshikazu, Hossain, Md. Jakir, Hisaeda, Yoshio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055166/
https://www.ncbi.nlm.nih.gov/pubmed/35517485
http://dx.doi.org/10.1039/d0ra05295g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055166/
https://www.ncbi.nlm.nih.gov/pubmed/35517485
http://dx.doi.org/10.1039/d0ra05295g

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