Cargando…
Electrochemically driven, cobalt–carbon bond-mediated direct intramolecular cyclic and acyclic perfluoroalkylation of (hetero)arenes using X(CF(2))(4)X
A proof-of-concept for the one-step, synthetically challenging cyclic and acyclic perfluoroalkylation of (hetero)arenes driven by the valence change of a vitamin B(12) derivative as a cobalt catalyst in the presence of fluoroalkylating reagents (X(CF(2))(4)X) is presented. The consecutive formation...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055166/ https://www.ncbi.nlm.nih.gov/pubmed/35517485 http://dx.doi.org/10.1039/d0ra05295g |