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The mechanochemical Scholl reaction as a versatile synthesis tool for the solvent-free generation of microporous polymers

Herein we report the mechanochemical Scholl polymerization of 1,3,5-triphenylbenzene in a high speed ball mill. The reaction is conducted solvent-free, solely using solid FeCl(3). The resulting porous polymer was obtained in >99% yield after very short reaction times of only 5 minutes and exhibit...

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Detalles Bibliográficos
Autores principales: Krusenbaum, Annika, Grätz, Sven, Bimmermann, Sarah, Hutsch, Stefanie, Borchardt, Lars
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055252/
https://www.ncbi.nlm.nih.gov/pubmed/35518582
http://dx.doi.org/10.1039/d0ra05279e