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Binary catalytic system for homo- and block copolymerization of ε-caprolactone with δ-valerolactone
The combined interaction of 2,3,6,7-tetrahydro-5H-thiazolo[3,2-a] pyrimidine (ITU) as the organocatalytic nucleophile with YCl(3) as Lewis acid cocatalyst, generating ITU/YCl(3), was employed for homo- and copolymerization of ε-caprolactone (CL) with δ-valerolactone (VL). Poly(caprolactone) (PCL) an...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055323/ https://www.ncbi.nlm.nih.gov/pubmed/35518598 http://dx.doi.org/10.1039/d0ra04974c |