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Visible light-induced photocatalytic C–H ethoxycarbonylmethylation of imidazoheterocycles with ethyl diazoacetate

A visible light-mediated regioselective C3-ethoxycarbonylmethylation of imidazopyridines with ethyl diazoacetate (EDA) was achieved under mild reaction conditions. In contrast to the carbene precursors from α-diazoester a first C3-ethoxycarbonylmethylation of imidazopyridines via a radical intermedi...

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Detalles Bibliográficos
Autores principales: Bhattacharjee, Suvam, Laru, Sudip, Samanta, Sadhanendu, Singsardar, Mukta, Hajra, Alakananda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055643/
https://www.ncbi.nlm.nih.gov/pubmed/35519122
http://dx.doi.org/10.1039/d0ra05795a