Regioselective O/C phosphorylation of α-chloroketones: a general method for the synthesis of enol phosphates and β-ketophosphonates via Perkow/Arbuzov reaction

A regioselective O/C phosphorylation of α-chloroketones with trialkyl phosphites was performed for the first time, which employed solvent-free Perkow reaction and NaI-assisted Arbuzov reaction under mild conditions respectively. Versatile enol phosphates were prepared in good to excellent yields as...

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Detalles Bibliográficos
Autores principales: Cao, Yuepeng, Gao, Zhenhua, Li, Junchen, Bi, Xiaojing, Yuan, Ling, Pei, Chengxin, Guo, Yongbiao, Shi, Enxue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055934/
https://www.ncbi.nlm.nih.gov/pubmed/35521103
http://dx.doi.org/10.1039/d0ra05140c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055934/
https://www.ncbi.nlm.nih.gov/pubmed/35521103
http://dx.doi.org/10.1039/d0ra05140c

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