Reactions of triosmium and triruthenium clusters with 2-ethynylpyridine: new modes for alkyne C–C bond coupling and C–H bond activation

The reaction of the trimetallic clusters [H(2)Os(3)(CO)(10)] and [Ru(3)(CO)(10)L(2)] (L = CO, MeCN) with 2-ethynylpyridine has been investigated. Treatment of [H(2)Os(3)(CO)(10)] with excess 2-ethynylpyridine affords [HOs(3)(CO)(10)(μ-C(5)H(4)NCH=CH)] (1), [HOs(3)(CO)(9)(μ(3)-C(5)H(4)NC[double bond,...

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Detalles Bibliográficos
Autores principales: Joy, Md. Tuhinur R., Roknuzzaman, Hossain, Md. Emdad, Ghosh, Shishir, Tocher, Derek A., Richmond, Michael G., Kabir, Shariff E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056324/
https://www.ncbi.nlm.nih.gov/pubmed/35516016
http://dx.doi.org/10.1039/d0ra05393g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056324/
https://www.ncbi.nlm.nih.gov/pubmed/35516016
http://dx.doi.org/10.1039/d0ra05393g

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