Regioselective C–H sulfenylation of N-sulfonyl protected 7-azaindoles promoted by TBAI: a rapid synthesis of 3-thio-7-azaindoles

This paper describes the regioselective C-3 sulfenylation of N-sulfonyl protected 7-azaindoles with sulfonyl chlorides. In this transformation, dual roles of TBAI serving as both promoter and desulfonylation reagent have been demonstrated. The reaction proceeded smoothly under simple conditions to a...

Descripción completa

Detalles Bibliográficos
Autores principales: Hu, Jingyan, Ji, Xiaoming, Hao, Shuai, Zhao, Mingqin, Lai, Miao, Ren, Tianbao, Xi, Gaolei, Wang, Erbin, Wang, Juanjuan, Wu, Zhiyong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056539/
https://www.ncbi.nlm.nih.gov/pubmed/35518137
http://dx.doi.org/10.1039/d0ra06635d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056539/
https://www.ncbi.nlm.nih.gov/pubmed/35518137
http://dx.doi.org/10.1039/d0ra06635d

Ejemplares similares