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Regio- and stereoselective thiocyanatothiolation of alkynes and alkenes by using NH(4)SCN and N-thiosuccinimides

A highly regioselective thiocyanatothiolation of alkynes and alkenes assisted by hydrogen bonding under simple and mild conditions is developed. Our thiocyanatothiolation reagents are readily available ammonium thiocyanate and N-thiosuccinimides. This metal-free system offers good chemical yields fo...

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Detalles Bibliográficos
Autores principales: Qi, Liang, Liu, Shiwen, Xiao, Linxia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056709/
https://www.ncbi.nlm.nih.gov/pubmed/35515071
http://dx.doi.org/10.1039/d0ra06913b