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Formation of trisubstituted buta-1,3-dienes and α,β-unsaturated ketones via the reaction of functionalized vinyl phosphates and vinyl phosphordiamidates with organometallic reagents

We studied the reactions of vinyl phosphates and vinyl phosphordiamidates containing an ester functional group with organometallic reagents. We found that the functionalized vinyl phosphates were smoothly converted into tri- and tetrasubstituted buta-1,3-dienes via the reaction with aryllithium reag...

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Detalles Bibliográficos
Autores principales: Oeser, Petr, Koudelka, Jakub, Dvořáková, Hana, Tobrman, Tomáš
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056830/
https://www.ncbi.nlm.nih.gov/pubmed/35515642
http://dx.doi.org/10.1039/d0ra07472a