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Cylindrical macrocyclic compounds synthesized by connecting two bowl-shaped calix[3]aramide moieties: structures and chiroptical properties

Calix[3]aramide-based macrocycles 1 were successfully synthesized by a Glaser coupling reaction of two meta-calix[3]aramide moieties that have three ethynyl groups. The obtained macrocycles have stereoisomers: an enantiomeric pair and a meso form based on a combination of amide bond directions in th...

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Detalles Bibliográficos
Autores principales: Sakagami, Ryoko, Saito, Yuuki, Mori, Ryuichi, Satake, Misa, Okayasu, Misaki, Kikkawa, Shoko, Hikawa, Hidemasa, Azumaya, Isao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056864/
https://www.ncbi.nlm.nih.gov/pubmed/35514401
http://dx.doi.org/10.1039/d0ra07060b