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Addition of 1,3-dicarbonyl compounds to terminal alkynes catalyzed by a cationic cobalt(iii) complex
The Nakamura reaction using a cationic cobalt(iii) complex, [Cp*Co(CH(3)CN)(3)][SbF(6)](2) as the catalyst under neutral and aerobic conditions at 110 °C has been described. In solution, the complex is expected to lose a hemilabile acetonitrile ligand to produce a highly electron-deficient cobalt(ii...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056990/ https://www.ncbi.nlm.nih.gov/pubmed/35517105 http://dx.doi.org/10.1039/d0ra05923d |