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Catalyst-free regioselective acetylation of primary hydroxy groups in partially protected and unprotected thioglycosides with acetic acid

Highly regioselective acetylation of primary hydroxy groups in thioglycoside derivatives with gluco- and galacto-configurations was achieved by treatment with aqueous or anhydrous acetic acid (60–100% AcOH) at elevated temperatures (80–118 °C), avoiding complex, costly and time-consuming manipulatio...

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Detalles Bibliográficos
Autores principales: Abronina, Polina I., Malysheva, Nelly N., Zinin, Alexander I., Kolotyrkina, Natalya G., Stepanova, Elena V., Kononov, Leonid O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057154/
https://www.ncbi.nlm.nih.gov/pubmed/35517942
http://dx.doi.org/10.1039/d0ra07360a