Cargando…

Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl(3)

Herein, we report a ring-opening 1,3-arylboration of aryl cyclopropanes using BCl(3) in the presence of arene nucleophiles. Formal 1,3-oxy arylation and 1,3-amino arylation of the arylcyclopropane via one-pot derivatization of the installed boron group were also achieved.

Detalles Bibliográficos
Autores principales: Kuboki, Yuichi, Arisawa, Mitsuhiro, Murai, Kenichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057229/
https://www.ncbi.nlm.nih.gov/pubmed/35515187
http://dx.doi.org/10.1039/d0ra08151e