Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl(3)

Herein, we report a ring-opening 1,3-arylboration of aryl cyclopropanes using BCl(3) in the presence of arene nucleophiles. Formal 1,3-oxy arylation and 1,3-amino arylation of the arylcyclopropane via one-pot derivatization of the installed boron group were also achieved.

Detalles Bibliográficos
Autores principales: Kuboki, Yuichi, Arisawa, Mitsuhiro, Murai, Kenichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057229/
https://www.ncbi.nlm.nih.gov/pubmed/35515187
http://dx.doi.org/10.1039/d0ra08151e
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author Kuboki, Yuichi
Arisawa, Mitsuhiro
Murai, Kenichi
author_facet Kuboki, Yuichi
Arisawa, Mitsuhiro
Murai, Kenichi
author_sort Kuboki, Yuichi
collection PubMed
description Herein, we report a ring-opening 1,3-arylboration of aryl cyclopropanes using BCl(3) in the presence of arene nucleophiles. Formal 1,3-oxy arylation and 1,3-amino arylation of the arylcyclopropane via one-pot derivatization of the installed boron group were also achieved.
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spelling pubmed-90572292022-05-04 Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl(3) Kuboki, Yuichi Arisawa, Mitsuhiro Murai, Kenichi RSC Adv Chemistry Herein, we report a ring-opening 1,3-arylboration of aryl cyclopropanes using BCl(3) in the presence of arene nucleophiles. Formal 1,3-oxy arylation and 1,3-amino arylation of the arylcyclopropane via one-pot derivatization of the installed boron group were also achieved. The Royal Society of Chemistry 2020-10-13 /pmc/articles/PMC9057229/ /pubmed/35515187 http://dx.doi.org/10.1039/d0ra08151e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Kuboki, Yuichi
Arisawa, Mitsuhiro
Murai, Kenichi
Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl(3)
title Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl(3)
title_full Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl(3)
title_fullStr Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl(3)
title_full_unstemmed Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl(3)
title_short Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl(3)
title_sort ring-opening 1,3-arylboration of arylcyclopropanes mediated by bcl(3)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057229/
https://www.ncbi.nlm.nih.gov/pubmed/35515187
http://dx.doi.org/10.1039/d0ra08151e
work_keys_str_mv AT kubokiyuichi ringopening13arylborationofarylcyclopropanesmediatedbybcl3
AT arisawamitsuhiro ringopening13arylborationofarylcyclopropanesmediatedbybcl3
AT muraikenichi ringopening13arylborationofarylcyclopropanesmediatedbybcl3

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