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New strategy for synthesis of hydroxyl-terminated poly(3-hexylthiophene) and its block copolymer using an η(3)-π-allyl hydroxyl-functionalized Ni(i) initiator
A novel hydroxyl-terminated π-allyl nickel initiator [η(3)-Ni(CH(2)CHCHCH(2)OCOCH(3))][BPh(F)(4)] is synthesized for the first time. (1)H-NMR analysis confirms that the Ni initiator possesses a typical π-allyl structure with a protected hydroxyl group. The Ni initiator is applied to synthesize hydro...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057512/ https://www.ncbi.nlm.nih.gov/pubmed/35515373 http://dx.doi.org/10.1039/d0ra07773a |