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New strategy for synthesis of hydroxyl-terminated poly(3-hexylthiophene) and its block copolymer using an η(3)-π-allyl hydroxyl-functionalized Ni(i) initiator

A novel hydroxyl-terminated π-allyl nickel initiator [η(3)-Ni(CH(2)CHCHCH(2)OCOCH(3))][BPh(F)(4)] is synthesized for the first time. (1)H-NMR analysis confirms that the Ni initiator possesses a typical π-allyl structure with a protected hydroxyl group. The Ni initiator is applied to synthesize hydro...

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Detalles Bibliográficos
Autores principales:	Min, Xin, Zhan, Changchao, Yan, Ping, Ye, Zhigang
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057512/ https://www.ncbi.nlm.nih.gov/pubmed/35515373 http://dx.doi.org/10.1039/d0ra07773a

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