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Divergent reactivity of divinylsilanes toward sulfonamides in different oxidative systems

Oxidative sulfonamidation of divinylsilanes with various sulfonamides in different solvents is reported. With t-BuOI as an oxidant, halogenation is the main process, whereas aziridines are the minor products. With NBS in CH(2)Cl(2) the products of bromination or bromosulfonamidation were obtained, w...

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Detalles Bibliográficos
Autores principales: Moskalik, Mikhail Yu., Astakhova, Vera V., Shainyan, Bagrat A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057569/
https://www.ncbi.nlm.nih.gov/pubmed/35520841
http://dx.doi.org/10.1039/d0ra07469a