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Divergent reactivity of divinylsilanes toward sulfonamides in different oxidative systems
Oxidative sulfonamidation of divinylsilanes with various sulfonamides in different solvents is reported. With t-BuOI as an oxidant, halogenation is the main process, whereas aziridines are the minor products. With NBS in CH(2)Cl(2) the products of bromination or bromosulfonamidation were obtained, w...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057569/ https://www.ncbi.nlm.nih.gov/pubmed/35520841 http://dx.doi.org/10.1039/d0ra07469a |