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Bismuth subsalicylate, a low-toxicity catalyst for the ring-opening polymerization (ROP) of l-lactide (l-LA) with aliphatic diol initiators: synthesis, characterization, and mechanism of initiation

The ring-opening polymerization (ROP) of l-lactide (l-LA) was induced by the catalytic action of bismuth subsalicylate (BiSS) using linear aliphatic diols [HO(CH(2))(n)OH, where n = 2, 3, 4, 5, 6, and 8] as initiators and chain transfer agents. The theoretical and experimental degree of polymerizati...

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Detalles Bibliográficos
Autores principales: Ortiz-Aldaco, María Guadalupe, Báez, José E., Jiménez-Halla, J. Oscar C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057703/
https://www.ncbi.nlm.nih.gov/pubmed/35516064
http://dx.doi.org/10.1039/d0ra05413e