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Photoaccelerated energy transfer catalysis of the Suzuki–Miyaura coupling through ligand regulation on Ir(iii)–Pd(ii) bimetallic complexes

Three bimetallic Ir(iii)–Pd(ii) complexes [Ir(ppy)(2)(bpm)PdCl(2)](PF(6)) (ppy = 2-phenylpyridine, 1), [Ir(dfppy)(2)(bpm)PdCl(2)](PF(6)) (dfppy = (4,6-difluorophenyl)pyridine, 2), and [Ir(pq)(2)(bpm)PdCl(2)](PF(6)) (pq = 2-phenylquinoline, 3) were synthesized by using 2,2′-bipyrimidine (bpm) as a br...

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Detalles Bibliográficos
Autores principales: Yao, Su-Yang, Cao, Man-Li, Zhang, Xiu-Lian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9058252/
https://www.ncbi.nlm.nih.gov/pubmed/35514913
http://dx.doi.org/10.1039/d0ra08547b