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A simplified approach for the metal-free polymerization of propylene oxide

Triethyl borane (Et(3)B), in combination with phosphazene-type superbases, has recently emerged as a powerful co-catalyst for the anionic polymerization of epoxides. Here, it is demonstrated that the monomer-activating property of Et(3)B can also compensate for the application of much gentler organo...

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Detalles Bibliográficos
Autores principales: Vogler, Charlotte, Naumann, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9058424/
https://www.ncbi.nlm.nih.gov/pubmed/35519681
http://dx.doi.org/10.1039/d0ra08970b