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Synthesis and characterization of methylammonium phosphates as crystalline approximants for anhydrous, low melting phosphate glasses

Low-melting methylammonium phosphate glasses are synthesized from crystalline starting agents. To this end crystalline tris(methylammonium) cyclotriphosphate [CH(3)NH(3)](3)P(3)O(9), was synthesized by a novel and simple synthesis route from P(4)O(10) and N-methylformamide. It, undergoes an irrevers...

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Detalles Bibliográficos
Autores principales: Mangstl, Martin, Wied, Jan Konrad, Weber, Johannes, Pritzel, Christian, Trettin, Reinhard, Schmedt auf der Günne, Jörn
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9059716/
https://www.ncbi.nlm.nih.gov/pubmed/35516152
http://dx.doi.org/10.1039/c8ra07736c