The mechanistic investigations of photochemical decarbonylations and oxidative addition reactions for M(CO)(5) (M = Fe, Ru, Os) complexes

The mechanisms for the photochemical CO-dissociation and the oxidative addition reactions are studied theoretically using three model systems: M(CO)(5) (M = Fe, Ru, and Os) and the CASSCF/Def2-SVP (fourteen-electron/ten-orbital active space) and MP2-CAS/Def2-SVP//CASSCF/Def2-SVP methods. The structu...

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Detalles Bibliográficos
Autores principales: Zhang, Zheng-Feng, Su, Ming-Der
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9059829/
https://www.ncbi.nlm.nih.gov/pubmed/35520498
http://dx.doi.org/10.1039/c8ra07669c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9059829/
https://www.ncbi.nlm.nih.gov/pubmed/35520498
http://dx.doi.org/10.1039/c8ra07669c

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