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The mechanistic investigations of photochemical decarbonylations and oxidative addition reactions for M(CO)(5) (M = Fe, Ru, Os) complexes

The mechanisms for the photochemical CO-dissociation and the oxidative addition reactions are studied theoretically using three model systems: M(CO)(5) (M = Fe, Ru, and Os) and the CASSCF/Def2-SVP (fourteen-electron/ten-orbital active space) and MP2-CAS/Def2-SVP//CASSCF/Def2-SVP methods. The structu...

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Detalles Bibliográficos
Autores principales:	Zhang, Zheng-Feng, Su, Ming-Der
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9059829/ https://www.ncbi.nlm.nih.gov/pubmed/35520498 http://dx.doi.org/10.1039/c8ra07669c

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