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Halide-free neodymium phosphate based catalyst for highly cis-1,4 selective polymerization of dienes

Neodymium-based Ziegler–Natta type catalytic systems are known to produce polydienes with high cis-1,4 content. It is generally believed that in Ziegler–Natta catalytic systems, a halide or pseudohalide, whether in the catalyst itself or a separate source, is required for the success of the polymeri...

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Detalles Bibliográficos
Autores principales: Ren, Yixin, Miller, Justin T., Polderman, Stefanie T., Vo, Trinh D., Wallace, Adele C. M., Cue, John Michael O., Tran, Sarah T., Biewer, Michael C., Stefan, Mihaela C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060247/
https://www.ncbi.nlm.nih.gov/pubmed/35518972
http://dx.doi.org/10.1039/c8ra10050k