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Reversible temperature-dependent high- to low-spin transition in the heme Fe–Cu binuclear center of cytochrome ba(3) oxidase
A reversible temperature-dependent high-spin to low-spin transition with T(1/2) = −60 °C has been observed in the resonance Raman spectra of the equilibrium reduced and photoreduced heme a(3) of the thermophilic ba(3) heme–copper oxidoreductase. The transition is based on the frequency shifts of the...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060599/ https://www.ncbi.nlm.nih.gov/pubmed/35514640 http://dx.doi.org/10.1039/c8ra09954e |