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Homogeneous hydroformylation of long chain alkenes catalyzed by water soluble phosphine rhodium complex in CH(3)OH and efficient catalyst cycling

The hydroformylation of long chain alkenes catalyzed by a water soluble Rh/TPPTS complex (TPPTS: sodium salt of sulfonated triphenylphosphine) in methanol was investigated. The mixture of rhodium precursor HRh(CO)(TPPTS)(3), ligand TPPTS, methanol and a long chain alkene becomes a single phase under...

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Detalles Bibliográficos
Autores principales: Liu, Yan-li, Zhao, Jian-gui, Zhao, Yuan-jiang, Liu, Hui-Min, Fu, Hai-yan, Zheng, Xue-li, Yuan, Mao-lin, Li, Rui-xiang, Chen, Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9061191/
https://www.ncbi.nlm.nih.gov/pubmed/35519978
http://dx.doi.org/10.1039/c8ra08787c