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Synthesis of N-aryl β-amino acid derivatives via Cu(ii)-catalyzed asymmetric 1,4-reduction in air

In the presence of the inexpensive and stable stoichiometric reductant polymethylhydrosiloxane (PMHS) as well as certain amounts of appropriate alcohol and base additives, the non-precious metal copper-catalyzed asymmetric 1,4-hydrosilylation of β-aryl or β-alkyl-substituted N-aryl β-enamino esters...

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Detalles Bibliográficos
Autores principales: Li, Min, Xia, Hong-Feng, Yang, Li-Yao, Hong, Tao, Xie, Lin-Jie, Li, Shijun, Wu, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062089/
https://www.ncbi.nlm.nih.gov/pubmed/35517703
http://dx.doi.org/10.1039/c9ra01203f