Cargando…

Synthesis of N-aryl β-amino acid derivatives via Cu(ii)-catalyzed asymmetric 1,4-reduction in air

In the presence of the inexpensive and stable stoichiometric reductant polymethylhydrosiloxane (PMHS) as well as certain amounts of appropriate alcohol and base additives, the non-precious metal copper-catalyzed asymmetric 1,4-hydrosilylation of β-aryl or β-alkyl-substituted N-aryl β-enamino esters...

Descripción completa

Detalles Bibliográficos
Autores principales:	Li, Min, Xia, Hong-Feng, Yang, Li-Yao, Hong, Tao, Xie, Lin-Jie, Li, Shijun, Wu, Jing
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062089/ https://www.ncbi.nlm.nih.gov/pubmed/35517703 http://dx.doi.org/10.1039/c9ra01203f

Ejemplares similares

Nickel-catalyzed asymmetric reductive arylation of α-chlorosulfones with aryl halides
por: Sun, Deli, et al.
Publicado: (2021)

Enantioselective synthesis of α-amino ketones through palladium-catalyzed asymmetric arylation of α-keto imines
por: Wen, Wei, et al.
Publicado: (2022)

Nickel-catalyzed asymmetric reductive aryl-allylation of unactivated alkenes
por: Lin, Zhiyang, et al.
Publicado: (2021)

Asymmetric Synthesis of Nortropanes via Rh-Catalyzed Allylic Arylation
por: Zhang, Yan, et al.
Publicado: (2022)

Efficient Cu-catalyzed intramolecular O-arylation for synthesis of benzoxazoles in water
por: Tang, Yanling, et al.
Publicado: (2020)

Asymmetric synthesis of dibenzo[b,d]azepines by Cu-catalyzed reductive or borylative cyclization
por: Rodríguez-Salamanca, Patricia, et al.
Publicado: (2021)

Ni-catalyzed asymmetric hydrogenation of N-aryl imino esters for the efficient synthesis of chiral α-aryl glycines
por: Liu, Dan, et al.
Publicado: (2020)

Manganese-Catalyzed Asymmetric Hydrosilylation of Aryl Ketones
por: Ma, Xiaochen, et al.
Publicado: (2017)

Asymmetric synthesis of aryl/vinyl alkyl carbinol esters via Ni-catalyzed reductive arylation/vinylation of 1-chloro-1-alkanol esters
por: Sun, Deli, et al.
Publicado: (2022)

Atroposelective synthesis of N-aryl peptoid atropisomers via a palladium(ii)-catalyzed asymmetric C–H alkynylation strategy
por: Wu, Yong-Jie, et al.
Publicado: (2021)

Nickel-catalyzed asymmetric reductive cross-coupling of α-chloroesters with (hetero)aryl iodides
por: DeLano, Travis J., et al.
Publicado: (2021)

Enantioselective synthesis of gem-diarylalkanes by transition metal-catalyzed asymmetric arylations (TMCAAr)
por: Jia, Tao, et al.
Publicado: (2017)

Mechanism of the Cu(II)-catalyzed benzylic oxygenation of (aryl)(heteroaryl)methanes with oxygen
por: Sterckx, Hans, et al.
Publicado: (2016)

Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids
por: Bandar, Jeffrey S., et al.
Publicado: (2016)

Copper-catalyzed asymmetric C(sp(2))–H arylation for the synthesis of P- and axially chiral phosphorus compounds
por: Yan, Shao-Bai, et al.
Publicado: (2023)

Cu-catalyzed asymmetric regiodivergent electrosynthesis and its application in the enantioselective total synthesis of (-)-fumimycin
por: Xie, Tian, et al.
Publicado: (2023)

Ni(ii)-catalyzed mono-selective ortho-arylation of unactivated aryl C–H bonds utilizing amino acids as a directing group
por: Cong, Zhanqing, et al.
Publicado: (2019)

Halogenated salt assisted Cu-catalyzed asymmetric 1,4-borylstannation of 1,3-enynes: enantioselective synthesis of allenylstannes
por: Ye, Jialin, et al.
Publicado: (2020)

Asymmetric synthesis of flavanols via Cu-catalyzed kinetic resolution of chromenes and their anti-inflammatory activity
por: Yang, Qingjing, et al.
Publicado: (2022)

Chiral Brønsted Acid‐Catalyzed Asymmetric Synthesis of N‐Aryl‐cis‐aziridine Carboxylate Esters
por: Bew, Sean P., et al.
Publicado: (2017)

Synthesis of Carbonyl-Containing Oxindoles via Ni-Catalyzed Reductive Aryl-Acylation and Aryl-Esterification of Alkenes
por: Ding, Zhengtian, et al.
Publicado: (2022)

Catalytic enantioselective synthesis of tetrasubstituted chromanones via palladium-catalyzed asymmetric conjugate arylation using chiral pyridine-dihydroisoquinoline ligands
por: Baek, Doohyun, et al.
Publicado: (2020)

Asymmetric synthesis of primary amines catalyzed by thermotolerant fungal reductive aminases
por: Mangas-Sanchez, Juan, et al.
Publicado: (2020)

Preparation of α-amino acids via Ni-catalyzed reductive vinylation and arylation of α-pivaloyloxy glycine
por: Tao, Xianghua, et al.
Publicado: (2020)

Decarboxylative Palladium(II)-Catalyzed Synthesis of Aryl Amidines from Aryl Carboxylic Acids: Development and Mechanistic Investigation
por: Rydfjord, Jonas, et al.
Publicado: (2013)

Palladium-catalyzed borylation of aryl (pseudo)halides and its applications in biaryl synthesis
por: Ji, Hong, et al.
Publicado: (2018)

Base-catalyzed synthesis of aryl amides from aryl azides and aldehydes
por: Xie, Sheng, et al.
Publicado: (2016)

Asymmetric Synthesis of N‐Substituted α‐Amino Esters from α‐Ketoesters via Imine Reductase‐Catalyzed Reductive Amination
por: Yao, Peiyuan, et al.
Publicado: (2021)

Chromium(II)-catalyzed enantioselective arylation of ketones
por: Wang, Gang, et al.
Publicado: (2016)

Cu-catalyzed N-3-Arylation of Hydantoins Using Diaryliodonium Salts
por: Neerbye Berntsen, Linn, et al.
Publicado: (2020)

Bifunctional thiosquaramide catalyzed asymmetric reduction of dihydro-β-carbolines and enantioselective synthesis of (−)-coerulescine and (−)-horsfiline by oxidative rearrangement
por: Sathish, Manda, et al.
Publicado: (2020)

Transition Metal Catalyzed Synthesis of Aryl Sulfides
por: Eichman, Chad C., et al.
Publicado: (2011)

Palladium(II)-Catalyzed Regioselective Ortho Arylation of sp(2) C—H Bonds of N-Aryl-2-amino Pyridine Derivatives
por: Koley, Moumita, et al.
Publicado: (2012)

Asymmetric synthesis of γ-branched amines via rhodium-catalyzed reductive amination
por: Wu, Zhao, et al.
Publicado: (2018)

A concise and efficient synthesis of benzimidazo[1,2-c]quinazolines through CuI-catalyzed intramolecular N-arylations
por: Pang, Xinlong, et al.
Publicado: (2015)

Cu-Catalyzed Arylation of Bromo-Difluoro-Acetamides by Aryl Boronic Acids, Aryl Trialkoxysilanes and Dimethyl-Aryl-Sulfonium Salts: New Entries to Aromatic Amides
por: Mkrtchyan, Satenik, et al.
Publicado: (2021)

Rhodium-catalyzed asymmetric 1,4-addition reactions of aryl boronic acids with nitroalkenes: reaction mechanism and development of homogeneous and heterogeneous catalysts
por: Miyamura, Hiroyuki, et al.
Publicado: (2017)

Asymmetric synthesis of multifunctional aryl allyl ethers by nucleophilic catalysis
por: Zhao, Shuai, et al.
Publicado: (2019)

α-Allyl-α-aryl α-Amino Esters in the Asymmetric Synthesis of Acyclic and Cyclic Amino Acid Derivatives by Alkene Metathesis
por: Curto, John M., et al.
Publicado: (2014)

Asymmetric β-arylation of cyclopropanols enabled by photoredox and nickel dual catalysis
por: Wang, Jianhua, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_6c1nh7q4vj5o8lapa74hpkslc0