Mechanistic insight into the catalytic hydrogenation of nonactivated aldehydes with a Hantzsch ester in the presence of a series of organoboranes: NMR and DFT studies

Mechanistic studies on the organoborane-catalyzed transfer hydrogenation of nonactivated aldehydes with a Hantzsch ester (diethyl-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate) as a synthetic NADH analogue were performed by NMR experiments and DFT calculations. In the reaction of benzaldehyde w...

Descripción completa

Detalles Bibliográficos
Autores principales: Hamasaka, Go, Tsuji, Hiroaki, Ehara, Masahiro, Uozumi, Yasuhiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062335/
https://www.ncbi.nlm.nih.gov/pubmed/35520935
http://dx.doi.org/10.1039/c9ra01468c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062335/
https://www.ncbi.nlm.nih.gov/pubmed/35520935
http://dx.doi.org/10.1039/c9ra01468c

Ejemplares similares