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High C(2)-C(4) selectivity in CO(2) hydrogenation by particle size control of Co-Fe alloy nanoparticles wrapped on N-doped graphitic carbon

A catalyst based on first-row Fe and Co with a record of 51% selectivity to C(2)-C(4) hydrocarbons at 36% CO(2) conversion is disclosed. The factors responsible for the C(2+) selectivity are a narrow Co-Fe particle size distribution of about 10 nm and embedment in N-doped graphitic matrix. These hyd...

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Detalles Bibliográficos
Autores principales: Peng, Lu, Jurca, Bogdan, Primo, Ana, Gordillo, Alvaro, Parvulescu, Vasile I., García, Hermenegildo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062353/
https://www.ncbi.nlm.nih.gov/pubmed/35521526
http://dx.doi.org/10.1016/j.isci.2022.104252