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Synthesis of Mg and Zn diolates and their use in metal oxide deposition

The synthesis of complexes [M(OCHMeCH(2)NMeCH(2))(2)] (5, M = Mg; 7, M = Zn) is described. Treatment of MeHNCH(2)CH(2)NMeH (1) with 2-methyloxirane (2) gave diol (HOCHMeCH(2)NMeCH(2))(2) (3), which upon reaction with equimolar amounts of MR(2) (4, M = Mg, R = Bu; 6, M = Zn, R = Et) gave 5 and 7. The...

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Detalles Bibliográficos
Autores principales: Frenzel, Peter, Preuß, Andrea, Bankwitz, Jörn, Georgi, Colin, Ganss, Fabian, Mertens, Lutz, Schulz, Stefan E., Hellwig, Olav, Mehring, Michael, Lang, Heinrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062479/
https://www.ncbi.nlm.nih.gov/pubmed/35515315
http://dx.doi.org/10.1039/c9ra00585d