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Asymmetric synthesis of multifunctional aryl allyl ethers by nucleophilic catalysis

Asymmetric allylic substitution of Morita–Baylis–Hillman (MBH) carbonates with less-nucleophilic phenols mediated by nucleophilic amine catalysis was successfully developed. A variety of substituted aryl allyl ethers were afforded with moderate to high yields with excellent enantioselectivities. The...

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Detalles Bibliográficos
Autores principales: Zhao, Shuai, Jin, Lei, Chen, Zhi-Li, Rui, Xue, He, Jia-Yi, Xia, Ran, Chen, Ke, Chen, Xiang-Xiang, Yin, Zi-Jian, Chen, Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9063376/
https://www.ncbi.nlm.nih.gov/pubmed/35520223
http://dx.doi.org/10.1039/c9ra00155g