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Single crystal growth and structure analysis of type-I (Na/Sr)–(Ga/Si) quaternary clathrates

Single crystals of (Na/Sr)–(Ga/Si) quaternary type-I clathrates, Na(8−y)Sr(y)Ga(x)Si(46−x), were synthesized by evaporating Na from a mixture of Na–Sr–Ga–Si–Sn in a 6 : 0.5 : 1 : 2 : 1 molar ratio at 773 K for 12 h in an Ar atmosphere. Electron-probe microanalysis and single-crystal X-ray diffractio...

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Detalles Bibliográficos
Autores principales: Urushiyama, Hironao, Morito, Haruhiko, Yamane, Hisanori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064156/
https://www.ncbi.nlm.nih.gov/pubmed/35516297
http://dx.doi.org/10.1039/c9ra01489f